Abstract

TKACH, Volodymyr V. et al. Mechanism of the electroanalytical performance of 2,7-bis (ferrocenyl-ethinyl) fluorene-9-one to electro-detection of hydrazine and its mathematical description. Rev. colomb. cienc. quim. farm. [online]. 2015, vol.44, n.2, pp.208-219. ISSN 0034-7418.  https://doi.org/10.15446/rcciquifa.v44n2.56294.

For the process of hydrazine electrooxidation over the layer of ferrocene-carbonylic derivative, the electroanalytic functionmechanism has been suggested. Also there has been developed and analyzed (by means of linear stability theory and bifurcation analysis) the mathematical model, capable to describe the processes in the system. The results of the modeling have been compared with experimental and theoretical for analogous systems

Keywords : hydrazine; 2,7-bis-(ferrocenil-ethynyl)-fluoren-9-one; electrochemical sensors; electrochemical oscillations; linear stability theory.

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