SciELO - Scientific Electronic Library Online

 
vol.48 número1El CdCl2 tiene un influjo celular cinético de orden cero e induce citotoxicidad y genotoxicidad a bajas concentraciones en leucocitos humanos in vitroAnálisis teórico de la posibilidad de la detección electroquímica de la sacarina, asistida por oxihidróxido de vanadio índice de autoresíndice de materiabúsqueda de artículos
Home Pagelista alfabética de revistas  

Servicios Personalizados

Revista

Articulo

Indicadores

Links relacionados

  • En proceso de indezaciónCitado por Google
  • No hay articulos similaresSimilares en SciELO
  • En proceso de indezaciónSimilares en Google

Compartir


Revista Colombiana de Ciencias Químico - Farmacéuticas

versión impresa ISSN 0034-7418

Resumen

TKACH, Volodymyr V. et al. The mathematical description for the process of the electrochemical detection of ascorbic acid over a conducting polymer, doped by a triiodide ion. Rev. colomb. cienc. quim. farm. [online]. 2019, vol.48, n.1, pp.159-169. ISSN 0034-7418.  https://doi.org/10.15446/rcciquifa.v48n1.80072.

The function of the conducting polymer, doped by triiodide ion in the electrochemical determination of the ascorbic acid has been mathematically evaluated. The mathematical model, correspondent to the system, was developed and analyzed by linear stability theory and bifurcation analysis. It was confirmed that the conducting polymer might be an excellent electrode modifier for ascorbic acid determination. The triiodide ion acts as the active substance, and the conducting polymer, as a mediator. The stable steady-state is easy maintain, which is correspondent to the vast zone of the linear dependence between the drug concentration and electrochemical parameter The possibility of oscillatory and monotonic instabilities has also been verified.

Palabras clave : Ascorbic acid; electrochemical sensors; conducting polymer; triiodide; electrooxidation; stable steady-state.

        · resumen en Portugués     · texto en Portugués     · Portugués ( pdf )