Resumo

POVEDA-JARAMILLO, Juan-Carlos et al. CHEMICAL CHARACTERIZATION OF THE ASPHALTENES FROM COLOMBIAN COLORADO LIGHT CRUDE OIL. C.T.F Cienc. Tecnol. Futuro [online]. 2016, vol.6, n.3, pp.105-122. ISSN 0122-5383.

ABSTRACT In the present work, we report the chemical characterization of asphaltenes from a light Colombian crude oil, 36° API, Colorado Crude Oil (CCO). Asphaltenes of CCO were extracted using the standard ASTM procedure, ASTM D6560-12. The approach to the chemical composition of asphaltenes was carried out by using elemental analysis (C, H, N, O, S), Fourier transform infrared spectroscopy (FT-IR), Raman Spectroscopy (RS), Matrix Assisted Laser Desorption Ionization - Time of Flight (MALDI-TOF) mass spectrometry, and proton and carbon nuclear magnetic resonance spectroscopy (¹H- and ¹³C-NMR). Finally, the crystallite parameters of nanoaggregates of CCO asphaltenes in solid phase were calculated using X-ray powder diffraction data. The average diameters of aromatic layers L₀ calculated from XRD and Raman were compared together and proved to be in good agreement. Average molecular parameters AMPs were calculated from elemental analysis, NMR and Raman spectroscopies, and X-ray diffractometry.

Palavras-chave : Asphaltenes; Chemical characterization; Average molecular parameters.

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