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DYNA

versão impressa ISSN 0012-7353versão On-line ISSN 2346-2183

Dyna rev.fac.nac.minas vol.88 no.218 Medellín jul./set. 2021  Epub 24-Mar-2022

https://doi.org/10.15446/dyna.v88n218.90284 

Articles

Effects of pretreatment and leaching medium on the extraction efficiency of Au and Ag from a chalcopyrite leaching by-product

Efectos del medio de pretratamiento y lixiviación sobre la eficiencia de extracción de Au y Ag de un subproducto de la lixiviación de calcopirita

Marleth Roxana Garza-Román a  
http://orcid.org/0000-0001-5178-5643

Francisco Raúl Carrillo-Pedroza a  
http://orcid.org/0000-0002-0413-0676

Nallely Guadalupe Picazo-Rodríguez a  
http://orcid.org/0000-0002-5780-2747

Ma de Jesús Soria-Aguilar a  
http://orcid.org/0000-0003-3910-7772

Isaías Almaguer-Guzmán b  
http://orcid.org/0000-0003-4076-3697

Josué Chaidez-Félix b  
http://orcid.org/0000-0001-8200-4539

a Facultad de Metalurgia, Universidad Autónoma de Coahuila, Coahuila, México. mroxana.garza@hotmail.com, raul.carrillo@uadec.edu.mx, nallely_pikzo@hotmail.com, ma.soria@uadec.edu.mx

b Peñoles, CIDT-SEPSA, Torreón, México. isaias_almaguer@penoles.com.mx, josue_chaidez@penoles.com.mx


Abstract

Precious metals such as gold (Au) and silver (Ag) are essential to our modern society due to their unique properties, such as high conductivity and physical and chemical resistance. They are often concentrated in by-products during the extraction of base metals. In the present work, a chalcopyrite leaching residue, constituted mainly of elemental sulfur and jarosites, was subjected to different pretreatments and leached with different leaching media to recover Au and Ag. The solid residue was pretreated by desulfurization, peroxidation, desulfurization+peroxidation and leached with cyanide, cyanide+glycine, and glycine. For comparison, samples without pretreatment were also leached using the same leaching media. Changes in the mineralogical species were followed to explain the effects of pretreatment and leaching medium on the dissolution of Au and Ag. Results indicate that the highest extraction of gold and silver (Au:99.50%, Ag:46.71%) is achieved by using a combined desulfurization+peroxidation pretreatment and cyanide as leaching medium.

Keywords: cyanidation; glycine; precious metals; chalcopyrite leaching by-product

Resumen

Los metales preciosos como el oro (Au) y la plata (Ag) son esenciales para nuestra sociedad moderna debido a sus propiedades únicas como alta conductividad, resistencia física y química. A menudo se concentran en subproductos durante la extracción de metales básicos. En el presente trabajo, un residuo de lixiviación de calcopirita constituido principalmente por azufre elemental y jarositas fue sometido a diferentes pretratamientos y lixiviación con diferentes medios de lixiviación para recuperar Au y Ag. El residuo sólido se pretrató mediante desulfuración, peroxidación, desulfuración + peroxidación y se lixivió con cianuro, cianuro + glicina y glicina. A modo de comparación, las muestras sin tratamiento previo, también se lixiviaron utilizando el mismo medio de lixiviación. Se siguieron los cambios en las especies mineralógicas con el fin de explicar los efectos del medio de pretratamiento y lixiviación sobre la disolución de Au y Ag. Los resultados indican que la mayor extracción de oro y plata (Au: 99,50%, Ag: 46,71%) se logra mediante el uso de un pretratamiento combinado de desulfuración + peroxidación y cianuro como medio de lixiviación.

Palabras clave: cianuración; glicina; metales preciosos; subproducto de la lixiviación de calcopirita

1. Introduction

Mexico is considered one of the top producers of gold (Au) and silver (Ag) in the world, which has been possible due to its great mining potential in terms of mineral resources. The cyanide leaching process is the most widely used method for recovery of Au and Ag and is considered an efficient hydrometallurgical technology [1]. However, the hydrometallurgical extraction of these high value elements from copper iron-sulfide mineral by-products becomes difficult in the presence of jarosites and/or elemental sulfur (products of leaching reactions) [2], since they act as cyanicides, thus affecting the effectiveness of cyanide to leach Au and Ag from sulphide ores [3].

Several works have been conducted to remove elements that cause a negative effect on the extraction efficiency of Au and Ag, for instance, the selective dissolution process toward removing elemental sulfur using organic solvents such as perchlorethylene, kerosene, clear oil, trichlorethylene, ethylcyclohexane, carbon tetrachloride, tetrachloroethane, and mixtures of these. This process is based on the chemical affinity between sulfur and organic solvents, which allows the formation of organosulfur compounds [4].

Other authors have reported the hydrothermal decomposition of jarosites in alkaline and acid media [5, 6]. It was found that in acid medium, the hydrothermal decomposition of jarosites in the range 90-250 ºC promotes the formation of soluble sulfate species [5]. On the other hand, the hydrothermal decomposition of an industrial Najarosite (150 g/t Ag) was conducted in alkaline medium at 60 ºC; NaOH and Ca(OH)2 were employed as alkalizing agents to obtain different pH (8, 9, 10, and 11). Best results were obtained at pH 11 for both alkalizing agents. Hydrothermal decomposition of the jarosite was completed after 3 min and 40 min, when NaOH and Ca (OH)2 were used to adjust pH to 11, respectively. In the former, the decomposition process was controlled by the chemical reaction, while in the second, the decomposition process was controlled by diffusion. This latter was supported by the formation of a product layer, which renders the reaction between hydroxyl ions and the unreacted jarosite core difficult [6].

It is noteworthy that Au and Ag may be present in refractory species (for example, pyrargyrite); for this reason, some researchers have proposed an oxidation pretreatment process with ozone for the extraction of such metals (O3) [3,7]. Sodium persulfate (Na2S2O8) has been utilized as an oxidizing agent for the recovery of metals in alkaline solutions [8,9]; in addition, it has been employed to dissolve copper sulphides in acidic pH solutions [8].

Although the conventional cyanidation process is known to be the most efficient in gold extraction, cyanide nevertheless has the disadvantage of being harmful to the environment and health. Based on the above, other researchers have searched for alternative leaching agents to cyanide, among which glycine is highlighted. Glycine has the advantage of not being toxic, and it has been demonstrated that a mixture of glycine and cyanide can enhance the efficiency of Au and Ag extraction from copper ores and concentrates [10,11]. In this context, the present work was aimed at investigating the effect of the pretreatment (desulfurization, peroxidation, desulfurization+peroxidation) and the leaching medium (cyanide, glycine, and cyanide+glycine) on the efficiency of Au and Ag extraction from a chalcopyrite leaching by-product.

In this work, the effect of the composition of a direct leaching residue of chalcopyrite (composed mainly of jarosite, elemental sulfur, and valuable metals such as gold and silver) is analyzed. It is important to mention that there are no studies, to our knowledge, that report information on waste treatments with the composition or mixture of components employed in this work. Individually, as previously mentioned, elemental sulfur and jarosite have been studied, since they affect the extraction of gold and silver. In this regard, this work exposes the effect of jarosite and elemental sulfur and the impact of the pre-treatments for their removal or transformation into compounds that do not inhibit the extraction of gold and silver. Cyanide is used as leaching agent, and glycine, as an assistant of cyanide in the recovery of gold and silver, with the aim of reducing the use of cyanide.

2. Experimental procedure

The residue used in the present investigation was obtained from the leaching process of a chalcopyrite concentrate (particle size D90 = 47.61 µm), Table 1 shows the chemical analysis of the chalcopyrite concentrate and Table 2, the mineralogical reconstruction of this concentrate.

Table 1 Chemical analysis of the chalcopyrite concentrate (wt. %). 

Source: The authors.

Table 2 Mineralogical reconstruction of the chalcopyrite concentrate. 

Source: The authors.

The leaching experiments were carried out in a 200-L, 316-L stainless steel reactor, which can operate at 0.15 MPa. It was equipped with a chemical seal, a stirring system and four deflectors, a controlled cooling/heating jacket, a pressure transmitter and a resistance temperature detector, and a Graphtec Data logger.

The experimental procedure began with the addition of hot water (80 °C) to the reactor and the initiation of the agitation system, which was set at a low revolution speed; then, the chalcopyrite concentrate was fed into the reactor, followed by sulfuric acid. After the addition of these materials, a 2-min air purge was performed; then, the reactor was closed and pressurized to 1 kg/cm2 with medicinal oxygen, and the agitation velocity was set at 550 rpm.

The chalcopyrite leaching by-product obtained in the leaching of chalcopyrite (particle size D90 = 16.92 µm), used in the present work is mainly constituted of plumbojarosite, hydroniumjarosite, and elemental sulfur; this solid residue will be referred hereafter as Material M1. The solid residue was characterized by inductively coupled plasma optical emission spectroscopy (ICP-OES), X-ray fluorescence spectrometry (XRF), and X-ray diffraction (XRD) using a PerkinElmer Optima ICP-OES spectrometer, a Rigaku Primus XRF spectrometer, and a Panalytical Emperyrean X-ray diffractometer, respectively. The mineralogical reconstruction of Material M1 was determined from the results of ICP, XRF, and XRD using HSC 8.0 software and the Species Converter module.

Solid products were characterized in each processing step for mass balance. Experiments consisted of two steps: pretreatment of the chalcopyrite leaching by-product and recovery of precious metals (Au, Ag) from the solid residue.

The experimental procedure was carried out as follows: first, the Material M1 without any treatment was leached with glycine (C2H5NO2 under certain conditions (C2H5NO2 =1M, pH=11, H2O2=1%, T=50 ºC, t= 24 h), this to determine whether glycine would be used in combination with cyanide.

Subsequently, Material M1 was subjected to three treatments, whose experimental conditions are shown in Fig. 1:

Source: The authors.

Figure 1 Schematic flow diagram of the methodology used in the present work. 

  • a) Desulfurization treatment. The samples were placed in a vessel and perchloroethylene was added following the procedure describe by Haver and Wong (1971) [12].

  • b) Preoxidation. Material M1 sample (S/L=10%) was treated with NaOH 1M, Na₂S₂O₈ 0.1M, at a temperature of 323 K and pH=1.

  • c) Desulfurization + Preoxidation. The desulfurized sample was treated with NaOH 1M, Na₂S₂O₈ 0.1M, at a temperature of 323 K and pH=1.

Each treated residue was subjected to cyanide and glycine cyanide leaching, where 300 g of material was leached into bottles, under the following conditions: pH=11, NaCN=0.06 M, T=298 K, t=24 h, C2H5NO2 =0.06 M.

Finally, chemical analysis was realized using a PerkinElmer ICP optical emission spectrometer

Fig. 1 shows a schematic flow diagram of the experimental procedure used in the present investigation.

3. Results and discussion

3.1 Characterization of the as-received chalcopyrite leaching by-product

Table 3 shows the chemical composition of Material M1 determined by XRF (elemental sulfur, S°) and ICP (the rest of the elements).

Table 3 Chemical analysis of the as-received chalcopyrite leaching by-product (wt. %). 

Source: The authors.

A characteristic of the residue that was utilized in the present work is that it is constituted, for the most part, by elemental sulfur, which we can observe in another research works [13,14].

Table 4 shows the mineralogical reconstruction of Material M1 obtained from the results of ICP, XRD and XRF, with HSC 8.0 software and the Species Converter module.

Table 4 Mineralogical reconstruction of the as-received chalcopyrite leaching by-product. 

Source: The authors.

The mineralogical reconstruction of the materials in the characterization tables is determined by the results of X-ray diffraction and chemical analysis, using HSC 8.0 software in the Species Converter module.

As mentioned previously, the as-received chalcopyrite leaching by-product (Material M1) was subjected to different pretreatments and leached with different leaching media to recover Au and Ag. For comparison, an experiment without pretreatment was also conducted. The results obtained from these experiments are presented in the following sections.

3.2 Characterization of the as-received chalcopyrite leaching by-product: without pretreatment

To investigate the effect of pretreatments, the as-received chalcopyrite leaching by-product (Material M1) was firstly leached with cyanide, cyanide+glycine, and glycine, without being subjected to any pretreatment. Fig. 2 shows the recovery of Au and Ag from the solid residue with the different leaching media; as can be observed, highest extraction efficiency is obtained with cyanide.

Source: The authors.

Figure 2 Extraction of Au, Ag and S° from the as-received chalcopyrite leaching by-product without pretreatment, by leaching with: cyanide (black), cyanide+glycine (dark gray), and glycine (light gray). 

As can be observed in Table 4, the chalcopyrite leaching by-product is constituted mainly of elemental sulfur (S˚), plumbojarosite (PJ), hydroniumjarosite (HJ), and amorphous material (AM), the latter composed mainly of sulfur and amorphous iron and, to a lesser extent, quartz (SiO2) and molybdenite (MoS2). These latter two species are designated as “others” in Table 5.

Table 5 Mineralogical analysis of chalcopyrite leaching by-product, before (M1) and after leaching with cyanide (CN M1), cyanide+glycine (CN+GLI M1), glycine (GLI M1). 

Source: The authors.

It is important to mention that species designated as “others” in Table 5 do not have a significant effect on the efficiency of the leaching process. In addition, it is noteworthy to indicate that the chemical analysis of the solid residue leached with glycine was not available; thus, the chemical analysis of the liquid used to extract Au and Ag was considered.

As observed in Fig. 2, the extraction of Au and Ag is low. Some authors have reported that, during the cyanidation process, Ag is frequently associated with Au, resulting in cyanide and oxygen consumption and in a simultaneous dissolution of Au and Ag, as shown in Equations 1 and 2 [15]:

It has been also reported that sulphur minerals are soluble in solutions with cyanide and oxygen; some sulfur-based species may be present in the leaching solution. A high consumption of the reagent occurs due to the presence of these species under conventional gold-cyanide leaching conditions; in addition, the dissolution rate of silver is usually slower than that of gold, which affects the leaching kinetics and the extraction of the desired metals [1]. Sulfur-containing solids can react with cyanide, forming thiocyanate, thus negatively affecting the availability of cyanide to leach precious metals [16]; this reaction is described by Equation 3 [17]:

Silver (Ag) dissolution is affected by the presence of elemental sulfur (S°), since this latter promotes the precipitation of silver thiocyanate [18], as shown in Equation 4 [17]:

Fig. 3 shows the species distribution diagram calculated as a function of pH using the Medusa computer program [19], considering the species concentrations employed in the experiments. As can be observed, thiocyanate is thermodynamically stable in the pH range of 1-12.

Source: The authors.

Figure 3 Species distribution diagram calculated for the system CN--SCN- [19]. 

When glycine is added to the leaching medium, the extraction of S° is low; this could be indicative of the adsorption of glycine on the S° surface, which may inhibit its dissolution; therefore, the reactions of Equations 3 and 4 will occur, to a lesser degree, in the presence of glycine. Regarding the presence of jarosite in Material M1, some studies have reported that the low recovery of Ag in mine tailings is due to that silver is occluded within the plumbojarosite lattice structure [20]. One of the problems involved in the jarosite precipitation process is the loss of significant amounts of silver, lead, zinc, and copper, which can be incorporated or assimilated into the jarosite structure. In this context, jarosite-type compounds represent an attractive source of silver and other precious metals, in that the amount of silver in these compounds is about 250 g/t Ag [21].

3.3 Chalcopyrite leaching by-product subjected to desulfurization pretreatment

The solid residue was then subjected to a desulfurization pretreatment, which was conducted under the experimental conditions shown in Fig. 1; this material was identified hereafter as Material M2. After performing this pretreatment, Material M2 was leached with the different media (cyanide, cyanide+glycine, glycine).

Fig. 4 shows the effects of the leaching medium on the recovery of silver and gold from Material M2. As can be observed, the highest recovery of Au and Ag (90.50% and 46.71%, respectively), is achieved in the cyanide-only leach system. The recoveries of these precious metals in the combined cyanide+glycine and glycine-only leach systems were 82.22% and 34.16%, and 1.91% and 0%, respectively. In addition, the amounts of Fe dissolved in the cyanide-only, cyanide+glycine, and glycine-only leach systems were about 12.98%, 16.13% and 16.46%, respectively.

Source: The authors.

Figure 4 Extraction of Au, Ag and Fe from Material M2 by leaching with cyanide (black), cyanide+glycine (dark gray) and glycine (light gray). 

Table 6 shows the chemical composition and mineralogical species of Material M2. As can be observed, this material is mainly constituted of plumbojarosite, elemental sulfur, and amorphous material. This latter contains mostly sulfur and amorphous iron.

Table 6 Chemical composition and species of chalcopyrite leaching by-product (M1), with desulfurization pretreatment, before (M2) and after leaching with cyanide (CN M2), cyanide+glycine (CN+GLI M2) and glycine (GLI M2). 

Source: The authors.

*Note: Species designated as “others” correspond to those elements that do not affect the leaching process efficiency.

As can be observed, the recovery of precious metals from Material M2 is higher than that obtained from Material M1; this behavior can be related to the significant reduction of elemental sulfur by the desulfurization pretreatment. The decrease in the amount of sulfur improves the extraction of gold and, to a lesser extent, the extraction of silver. However, these results were not expected; therefore, the low extraction of silver in the presence of jarosites is attributed to the occlusion of the silver within the jarosite crystal structure.

On the other hand, the formation of iron oxides and/or insoluble hydroxides may occur either before or during leaching with cyanide (Equations 5 and 6) [17], but this is not always desirable, since these products can surround gold particles, significantly reducing the effectiveness of the gold recovery [21].

Fig. 5 shows the species distribution diagram for the Fe2+- Fe3+ - CN- system calculated by Medusa software, considering the species concentrations employed in the experiments. As can be observed, the reaction of iron with cyanide decreases the availability of cyanide [19].

Source: The authors.

Figure 5 Species distribution diagram calculated by Medusa for the system Fe3+- Fe2+- CN- system. 

As observed in Figs. 2 and 4, the extractions of Au and Ag in the glycine-only leach system are marginal compared to those obtained in the combined cyanide+glycine leach system. This behavior suggests that the recovery of these precious metals with the lixiviant mixture of cyanide and glycine is mainly attributed to the effect of cyanide. For this reason, to evaluate the effectiveness of gold and silver extraction in further experiments, only leach systems with either cyanide or glycine were considered.

3.4 Chalcopyrite leaching by-product subjected to peroxidation pretreatment

The as-received chalcopyrite leaching by-product was subjected to peroxidation pretreatment; this sample is referred hereafter as Material M3. After conducting peroxidation pretreatment, Material M3 was leached using cyanide and glycine as leaching media. As observed in Fig. 6, the extractions of Au and Ag in the cyanide-only leach system were 99.50% and 6.04%, respectively, which were significantly higher than those obtained in the glycine-only leach system (0% Au and 8% Ag). These results indicate that glycine is less effective than cyanide in gold and silver recovery.

Source: The authors.

Figure 6 Effect of leaching media on the extraction of Au, Ag, Sº and Fe from Material M3: cyanide (black) and glycine (gray). 

Regarding the dissolution of S°, the amounts obtained by cyanide leaching and glycine leaching were 29.52% and 27.30%, respectively. In the case of Fe dissolution, the values obtained were 3.48% and 0.23%, respectively, when leaching was conducted with cyanide and glycine. As can be observed in Table 7, there is a significant amount of amorphous material in the solid residue. From the mineralogical reconstruction of Material M3, it was found that the predominant species is argentojarosite.

Table 7 Chemical composition and species of chalcopyrite leaching by-product (M1), with peroxidation pretreatment, before (M3) and after leaching with cyanide (CN M3) and glycine (GLI M3). 

Source: The authors.

*Note: Species designated as “others” correspond to those elements that do not affect the leaching process.

It is notable that the extraction of gold from Material M1 (without pretreatment) is higher than that obtained from Material M3 (with peroxidation pretreatment). This result suggests that peroxidation occurring in alkaline medium allows the release of gold from elemental sulfur due to the reaction of this later with NaOH, which promotes the formation of Na2S according to Equation 7:

Leaching of Material M3 with glycine causes a reduction of the unidentified material (Table 7), which may allude to the low silver extraction, since this latter is commonly associated with one or more minerals such as potassium jarosite, plumbojarosite, iron oxides and fine-grained silica. The recovery of silver usually decreases during hydrometallurgical processes such as cyanidation, when silver is often found as argentojarosite or as different varieties of oxides and sulfides [22]. Some materials are depleted after leaching; however, jarosite is not affected.

3.5 Chalcopyrite leaching by-product subjected to a combined desulfurization-peroxidation pretreatment

Material M2 (with desulfurization) was subjected to a peroxidation pretreatment, obtaining a sample with a desulfurization+peroxidation pretreatment, which is referred hereafter as Material M4. Subsequent leaching of Material M4 was conducted with cyanide and glycine, considering that, in the combined cyanide+glycine leach system, only one of the lixiviants (cyanide) acts as the metal complexing agent of the precious metal. As observed in Fig. 7, about 69.84% Au and 1.93% Ag were extracted in the cyanide-only leach system; however, the extractions of Au and Ag in the glycine-only leach system were 30.53% and 0%, respectively.

Source: The authors.

Figure 7 Effect of leaching media on the extraction of gold and silver from Material M4: cyanide (black) and glycine (gray). 

The iron-dissolution percentages obtained in the cyanide-only and glycine-only leach systems were 6.699% and 0%, respectively. According to Table 8, this material is mainly composed of elemental sulfur and unidentified material. As previously mentioned, sulfur does not affect the extraction of Au; however, it does affect the extraction of Ag. The mineralogical reconstruction corresponding to the unidentified material suggests that this is mainly composed of sulfohydroxides

Table 8 Chemical composition and of chalcopyrite leaching by-product with desulfurization+peroxidation pretreatment, before (M4) and after leaching with cyanide (CN M4) and glycine (GLI M4). 

Source: The authors.

*Note: Species designated as “others” are elements that do not affect the leaching process. NA: Chemical analysis not available.

3.6 Summary

The results of the present investigation show that cyanide is the best leaching medium for the extraction of Au and Ag from the chalcopyrite leaching by-product. Fig. 8 presents a comparison of the gold and silver percentages extracted under the different leaching systems.

Source: The authors.

Figure 8 Effect of pretreatment on the gold and silver extraction from the chalcopyrite leaching by-product in the cyanide-only leach system: as-received (M1), desulfurization (M2), peroxidation (M3) and desulfurization+peroxidation (M4). 

As can be observed, desulfurization is the most effective pretreatment to achieve the highest extraction of gold and silver from the chalcopyrite leaching by-product. As mentioned previously, the presence of elemental sulfur during cyanidation is undesirable because it contributes to the precipitation of silver and affects cyanide permeability, thus affecting the recovery of precious metals.

4. Conclusions

The following conclusions can be drawn from the results of the present investigation:

  • In general, all of the pretreatments investigated enhance the extraction of gold and silver. However, they have different impacts on the elements affecting the leaching performance.

  • Desulfurization is the most effective pretreatment to achieve the highest extraction of gold and silver, which is indicative of that a certain amount of these metals is occluded in the elemental sulfur, affecting cyanide permeability. Therefore, sulfur removal can enhance gold and silver extraction.

  • The increase in the recovery of gold (99.50%) by the peroxidation pretreatment is possibly related with the sulfur- to-Na2S transformation in alkaline medium. On the other hand, the peroxidation pretreatment apparently is not capable of releasing the silver present in plumbojarosite, thus decreasing the amount of silver recovered. This jarosite-type compound is refractory for cyanidation; in addition, silver associates strongly with lead, but not with gold.

  • From the comparison between the effectiveness of desulfurization and the combined desulfurization+peroxidation pretreatment, it is concluded that this latter is less effective for the recovery of precious metals. This observation is supported by the lower gold and silver extraction obtained with the combined pretreatment. In addition, peroxidation of Material M1 has a detrimental effect mainly on the extraction of silver.

  • Highest extraction of gold and silver from the chalcopyrite leaching by-product is obtained when Material M1 is subjected to the desulfurization pretreatment and subsequent leaching with cyanide. Independently of material type or mineralogical species, cyanide leaching significantly improves gold extraction from the solid residue; however, glycine does not have any significant effect either on the extraction of gold or of silver.

On many occasions, residues with higher gold and silver grades are obtained; such is the case of the chalcopyrite leaching by-product that was used in the present work, which contained 1,608.9 g/t of silver and 4.66 g/t of gold. Therefore, it can be economically profitable to apply the procedures and results obtained in this article.

This project was carried out with the objective of studying the extraction of gold and silver contained in these two materials using cyanide, glycine, and a mixture of cyanide and glycine. Although glycine did not have a significant effect on the extraction of gold and silver, it does have a significant effect on cyanide consumption, which has an environmental impact, since the use of glycine would allow the generation of cleaner waste.

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M.R. Garza-Román, received the BSc. Eng. in Chemical Metallurgist and Materials Engineer in 2013, a MSc. in Metallurgy Science and Technology in 2020, all of them from the Faculty of Metallurgy, Universidad Autónoma de Coahuila, Mexico. Is a doctorate student in Materials Science and Technology in 2020 at the Faculty of Chemical Sciences, at the Universidad Autónoma de Coahuila, Mexico. ORCID 0000-0001-5178-5643

F.R. Carrillo-Pedroza, is a Dr. in Metallurgical Engineering. Research professor at the Faculty of Metallurgy, Universidad Autónoma de Coahuila, Mexico. His areas of interest and research are the hydrometallurgy of noble metals and base metals and the treatment of metallurgical waste and effluents. ORCID 0000-0002-0413-0676

N.G. Picazo-Rodríguez, received the BSc. Eng. in Chemical Metallurgist and Materials Engineer in 2013, MSc. in Metallurgy Science and Technology in 2016, all of them from the Faculty of Metallurgy. Dr. in Materials Science and Technology in 2019 at the Faculty of Chemical Sciences, all degrees were obtained at the Universidad Autónoma de Coahuila, Mexico.ORCID 0000-0002-5780-2747

M.J. Soria-Aguilar, is a Dra. of Science in Metallurgical and Ceramic Engineering. Professor and Researcher at the Faculty of Metallurgy, Universidad Autónoma de Coahuila, Mexico. His areas of interest and research are the characterization of materials, physical metallurgy and forming of materials. ORCID 0000-0003-3910-7772

I. Almaguer-Guzmán, received the BSc. Eng. in Metallurgical Engineer with a MSc. in Extractive Metallurgy. He has specialized in the extractive processes (hydro, pyro and / or electrometallurgical) of zinc, lead, copper, gold and silver, and their by-products. He is currently Manager of the Metallurgical Processes Area at the Peñoles Company's Technological Research and Development Center. ORCID 0000-0003-4076-3697

J. Cháidez-Félix, is a Dr. of Engineering Sciences specialized in the hydrometallurgical area of copper and zinc. He currently works as a researcher at the Center for Research and Technological Development of the company Peñoles. Its lines of research are based on the metallurgy of zinc, copper and iron, currently serving in areas of Direct Leaching, Conventional Leaching and Roasting of zinc concentrates in a Zinc Electrolytic Plant. ORCID 0000-0001-8200-4539

How to cite: Garza-Román, M.R., Carrillo-Pedroza, F.R., Picazo-Rodríguez, N.G., Soria-Aguilar, M.deJ., Almaguer-Guzmán. I. and Chaidez-Félix, J., Effects of pretreatment and leaching medium on the extraction efficiency of Au and Ag from a chalcopyrite leaching by-product.. DYNA, 88(218), pp. 119-126, July - September, 2021.

Received: September 01, 2020; Revised: May 06, 2021; Accepted: June 23, 2021

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