<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0120-6230</journal-id>
<journal-title><![CDATA[Revista Facultad de Ingeniería Universidad de Antioquia]]></journal-title>
<abbrev-journal-title><![CDATA[Rev.fac.ing.univ. Antioquia]]></abbrev-journal-title>
<issn>0120-6230</issn>
<publisher>
<publisher-name><![CDATA[Facultad de Ingeniería, Universidad de Antioquia]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0120-62302018000400016</article-id>
<article-id pub-id-type="doi">10.17533/udea.redin.n89a03</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Kinetics of nopyl acetate synthesis by homogeneously catalyzed esterification of acetic acid with nopol]]></article-title>
<article-title xml:lang="es"><![CDATA[Cinética de la síntesis de acetato de nopilo mediante esterificación de ácido acético con nopol homogéneamente catalizada]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Hurtado-Burbano]]></surname>
<given-names><![CDATA[Eliana Paola]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Villa-Holguín]]></surname>
<given-names><![CDATA[Aída Luz]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,Universidad de Antioquia Facultad de Ingeniería Departamento de Ingeniería Química]]></institution>
<addr-line><![CDATA[Medellín ]]></addr-line>
<country>Colombia</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>12</month>
<year>2018</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>12</month>
<year>2018</year>
</pub-date>
<numero>89</numero>
<fpage>16</fpage>
<lpage>25</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_arttext&amp;pid=S0120-62302018000400016&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_abstract&amp;pid=S0120-62302018000400016&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_pdf&amp;pid=S0120-62302018000400016&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[ABSTRACT The esterification of nopol with acetic acid to produce nopyl acetate using sulfuric acid as homogeneous catalyst was studied. The reactions were carried out in a batch reactor, at different temperatures (50, 60, 70 and 80 °C), catalyst concentrations (0.0184, 0.0275, 0.0367 and 0.0480 mol L-1) and molar ratio of acetic acid to nopol (1: 1, 1:2, 1:3 and 1: 4); the chemical equilibrium composition was measured at those reaction conditions. It was found that the equilibrium composition is a weak function of temperature, equilibrium conversion was 63, 68, 71 and 75% at 50, 60, 70 and 80°C, respectively. The reaction was described with a simple power-law model with a second-order kinetic model for both the forward and the backward reaction, using concentration and activities which were predicted by the Universal Functional group Contribution (UNIFAC) method for considering non-ideal behavior of the liquid phase. The forward reaction rate and the equilibrium constants increased with temperature; the relation of the pre-exponential factor with the catalyst amount was evaluated. The activation energy and pre-exponential factor estimated for the forward reaction using the kinetic model based on concentration, were respectively, 28.08 kJ mol-1 and 11126 L mol-1 h-1 with a concentration of catalyst of 0.0275 M. Using the kinetic model based on activities, the forward reaction rate constant was 28.56 kJ·mol-1 and the k  fo,act was 33860 L mol-1 h-1. The enthalpy (34.90 kJ mol-1) and the entropy (0.12 kJ mol-1 K-1) of reaction were determined using van&#8217;t Hoff equation.]]></p></abstract>
<abstract abstract-type="short" xml:lang="es"><p><![CDATA[RESUMEN Se estudió la esterificación de nopol con ácido acético para producir acetato de nopilo utilizando ácido sulfúrico como catalizador homogéneo. Los experimentos se llevaron a cabo en un reactor por lotes variando la temperatura (50, 60, 70 y 80 °C), la concentración del catalizador (0,0184, 0,0275, 0,0367 y 0,0480 mol L-1) y la relación molar de ácido acético a nopol (1: 1, 1:2, 1:3 y 1: 4); la composición del equilibrio químico se midió a las condiciones de reacción. La conversión de equilibrio fue 63, 68, 71 y 75% a 50, 60, 70 y 80°C, respectivamente. La reacción se describió con un modelo de potencia simple con un modelo de segundo orden en ambas direcciones, usando concentraciones y actividades, las cuales se predijeron con el método de contribución de grupos UNIFAC. Se determinaron las constantes de velocidad de la reacción directa y la constante de equilibrio, las cuales aumentaron con la temperatura; se evaluó la relación del factor pre-exponencial con la cantidad de catalizador. La energía de activación y el factor pre-exponencial estimados para la reacción hacia adelante usando el modelo basado en concentración fueron respectivamente 18,08 kJ mol-1 y 11126 L mol-1 h-1 con una concentración de catalizador de 0,0275 M. Usando el modelo basado en actividades la constante de velocidad directa fue 28,56 kJ·mol-1 y el factor pre-exponencial 33860 L mol-1 h-1. La entalpía (34,90 kJ mol-1) y la entropía (0,12 kJ mol-1 K-1) de reacción se determinaron usando la ecuación de van&#8217;t Hoff.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[Activity coefficients]]></kwd>
<kwd lng="en"><![CDATA[nopol]]></kwd>
<kwd lng="en"><![CDATA[reaction rate]]></kwd>
<kwd lng="en"><![CDATA[equilibrium constant]]></kwd>
<kwd lng="en"><![CDATA[sulfuric acid]]></kwd>
<kwd lng="es"><![CDATA[Coeficientes de actividad]]></kwd>
<kwd lng="es"><![CDATA[nopol]]></kwd>
<kwd lng="es"><![CDATA[velocidad de reacción]]></kwd>
<kwd lng="es"><![CDATA[constante de equilibrio]]></kwd>
<kwd lng="es"><![CDATA[ácido sulfúrico]]></kwd>
</kwd-group>
</article-meta>
</front><back>
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