<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0120-6230</journal-id>
<journal-title><![CDATA[Revista Facultad de Ingeniería Universidad de Antioquia]]></journal-title>
<abbrev-journal-title><![CDATA[Rev.fac.ing.univ. Antioquia]]></abbrev-journal-title>
<issn>0120-6230</issn>
<publisher>
<publisher-name><![CDATA[Facultad de Ingeniería, Universidad de Antioquia]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0120-62302020000200088</article-id>
<article-id pub-id-type="doi">10.17533/udea.redin.20190941</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Gas phase synthesis of dimethyl carbonate from CO2 and CH3OH over Cu-Ni/AC. A kinetic study]]></article-title>
<article-title xml:lang="es"><![CDATA[Síntesis en fase gaseosa de dimetil carbonato con CO2 y CH3OH sobre Cu-Ni/AC. Estudio cinético]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Arbeláez Pérez]]></surname>
<given-names><![CDATA[Oscar Felipe]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Domínguez Cardozo]]></surname>
<given-names><![CDATA[Sara]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Orrego Romero]]></surname>
<given-names><![CDATA[Andrés Felipe]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Villa Holguín]]></surname>
<given-names><![CDATA[Aída Luz]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Bustamante]]></surname>
<given-names><![CDATA[Felipe]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,Universidad Cooperativa de Colombia Facultad de Ingeniería ]]></institution>
<addr-line><![CDATA[Medellín ]]></addr-line>
<country>Colombia</country>
</aff>
<aff id="Af2">
<institution><![CDATA[,Universidad de Antioquia Facultad de Ingeniería Departamento de Ingeniería Química]]></institution>
<addr-line><![CDATA[Medellín ]]></addr-line>
<country>Colombia</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>06</month>
<year>2020</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>06</month>
<year>2020</year>
</pub-date>
<numero>95</numero>
<fpage>88</fpage>
<lpage>99</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_arttext&amp;pid=S0120-62302020000200088&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_abstract&amp;pid=S0120-62302020000200088&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_pdf&amp;pid=S0120-62302020000200088&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[ABSTRACT The catalytic activity for dimethyl carbonate formation from carbon dioxide and methanol over mono and bimetallic Cu:Ni supported on activated carbon is presented. Bimetallic catalysts exhibit higher catalytic activity than the monometallic samples, being Cu:Ni-2:1 (molar ratio) the best catalyst; X-Ray diffraction, transmission electron microscopy, and metal dispersion analysis provided insight into the improved activity. In situ FT-IR experiments were conducted to investigate the mechanism of formation of dimethyl carbonate from methanol and carbon dioxide over Cu-Ni:2-1. The kinetics of the direct synthesis of dimethyl carbonate in gas phase over Cu:Ni-2:1 supported on activated carbon catalyst was experimentally investigated at 12 bar and temperatures between 90 °C and 130 °C, varying the partial pressures of CO2 and methanol. Experimental kinetic data were consistent with a Langmuir-Hinshelwood model that included carbon dioxide and methanol adsorption on catalyst actives sites (Cu, Ni and Cu-Ni), and the reaction of adsorbed CO2 with methoxi species as the rate determining step. The estimated apparent activation energy was 94.2 kJ mol-1.]]></p></abstract>
<abstract abstract-type="short" xml:lang="es"><p><![CDATA[RESUMEN Se reporta la actividad catalítica en la formación de dimetil carbonato a partir de dióxido de carbono y metanol sobre catalizadores mono y bimetálicos de Cu-Ni soportado en carbón activado. Los catalizadores bimetálicos presentaron una mayor actividad catalítica que los monometálicos, siendo la muestra Cu:Ni-2:1 el mejor catalizador. La caracterización de los materiales mediante análisis de difracción de rayos X, microscopía electrónica de transmisión y dispersión metálica permitieron sugerir una explicación al porqué de su mejor desempeño. Se realizaron experimentos de FT-IR in situ para investigar el mecanismo de formación de carbonato de dimetilo a partir de metanol y dióxido de carbono sobre Cu-Ni: 2-1. Se estudió la cinética de la síntesis directa de dimetil carbonato en fase gaseosa sobre Cu:Ni-2:1 soportado en carbón activado, a 12 bar y temperaturas entre 90 °C y 130 °C, como función de la presión parcial del dióxido de carbono y del metanol. Los datos experimentales fueron consistentes con un mecanismo Langmuir-Hinshelwood, el cual incluyó la adsorción de dióxido de carbono y metanol sobre los sitios activos del catalizador (Cu, Ni, y Cu-Ni), siendo la reacción del dióxido de carbono adsorbido con las especies metoxi como etapa limitante. La energía de activación aparente estimada de la reacción fue 94,2 kJ mol-1.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[Methanol]]></kwd>
<kwd lng="en"><![CDATA[catalysts]]></kwd>
<kwd lng="en"><![CDATA[reaction mechanism]]></kwd>
<kwd lng="en"><![CDATA[reaction rate]]></kwd>
<kwd lng="en"><![CDATA[In situ FT-IR analysis]]></kwd>
<kwd lng="es"><![CDATA[Metanol]]></kwd>
<kwd lng="es"><![CDATA[catalizadores]]></kwd>
<kwd lng="es"><![CDATA[mecanismo de reacción]]></kwd>
<kwd lng="es"><![CDATA[velocidad de reacción]]></kwd>
<kwd lng="es"><![CDATA[análisis FT-IR in situ]]></kwd>
</kwd-group>
</article-meta>
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