<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0121-7488</journal-id>
<journal-title><![CDATA[Ciencia en Desarrollo]]></journal-title>
<abbrev-journal-title><![CDATA[Ciencia en Desarrollo]]></abbrev-journal-title>
<issn>0121-7488</issn>
<publisher>
<publisher-name><![CDATA[Universidad Pedagógica y Tecnológica de Colombia]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0121-74882017000100109</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[Methylene blue degradation over M-TiO2 photocatalysts (M= Au or Pt)]]></article-title>
<article-title xml:lang="es"><![CDATA[Degradación de azul de metileno sobre fotocatalizadores M-TiO2 (M = Au o Pt)]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Murcia Mesa]]></surname>
<given-names><![CDATA[Julie Joseane]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Guarín Romero]]></surname>
<given-names><![CDATA[Jhonatan Ricardo]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Cely Macías]]></surname>
<given-names><![CDATA[Ángela Carolina]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Rojas Sarmiento]]></surname>
<given-names><![CDATA[Hugo Alfonso]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Cubillos Lobo]]></surname>
<given-names><![CDATA[Jairo Antonio]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Hidalgo López]]></surname>
<given-names><![CDATA[María del Carmen]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Navío Santos]]></surname>
<given-names><![CDATA[José Antonio]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,Universidad Pedagógica y Tecnológica de Colombia UPTC Escuela de Ciencias Químicas Grupo de Catálisis]]></institution>
<addr-line><![CDATA[Tunja Boyacá]]></addr-line>
<country>Colombia</country>
</aff>
<aff id="Af2">
<institution><![CDATA[,Universidad de Sevilla Consejo Superior de Investigaciones Científicas CSIC Instituto de Ciencia de Materiales de Sevilla (ICMS),]]></institution>
<addr-line><![CDATA[Seville ]]></addr-line>
<country>Spain</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>06</month>
<year>2017</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>06</month>
<year>2017</year>
</pub-date>
<volume>8</volume>
<numero>1</numero>
<fpage>109</fpage>
<lpage>117</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_arttext&amp;pid=S0121-74882017000100109&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_abstract&amp;pid=S0121-74882017000100109&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_pdf&amp;pid=S0121-74882017000100109&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[Abstract In this study it was evaluated the methylene blue degradation over TiO2 modified by sulfation and Au or Pt addition. These materials were synthesized by photodeposition method and then were widely characterized by different techniques. In general, it was found that Au or Pt particles size distribution can be effectively controlled modifying the deposition time. It was also found that metal particle size and dye adsorption on TiO2 surface, are important factors influencing the methylene blue degradation rate. The highest dye degradation was obtained on Au-S-TiO2 photocatalyst prepared by using 120 min of deposition time; the highest effectiveness of this material in the methylene blue degradation can be mainly due to a combined effect between the presence of gold nanoparticles acting as a sink for the electrons photogenerated during the catalytic reaction and the better adsorption of the dye over the S-TiO2 surface partially covered by gold particles with the largest sizes.]]></p></abstract>
<abstract abstract-type="short" xml:lang="es"><p><![CDATA[Resumen En este estudio se evaluó la degradación de azul de metileno sobre TiO2 modificado por sulfatación y adición de Au o Pt. Estos materiales fueron sintetizados a través del método de fotodeposición y caracterizados usando diferentes técnicas. En general, se encontró que la distribución de tamaño de partícula de Au o Pt se puede controlar efectivamente modificando el tiempo de fotodeposición. Se encontró también que factores como el tamaño de partícula metálica y la adsorción del colorante sobre la superficie del TiO2 influencian de manera importante la velocidad de degradación del azul de metileno. La mayor degradación del colorante se obtuvo usando el fotocatalizador Au-S-TiO2 preparado con un tiempo de deposición de 120 min; la alta efectividad de este material en la degradación del azul de metileno se debe principalmente a un efecto combinado entre la presencia de partículas de oro que actúan como colectores de los electrones fotogenerados durante la reacción catalítica y a la mejor adsorción del colorante sobre la superficie del S-TiO2 cubierta parcialmente por partículas de oro con el mayor tamaño.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[Methylene blue]]></kwd>
<kwd lng="en"><![CDATA[photodegradation]]></kwd>
<kwd lng="en"><![CDATA[sulfated TiO2]]></kwd>
<kwd lng="en"><![CDATA[M-TiO2]]></kwd>
<kwd lng="en"><![CDATA[photocatalysts]]></kwd>
<kwd lng="es"><![CDATA[Azul de metileno]]></kwd>
<kwd lng="es"><![CDATA[fotodegradación]]></kwd>
<kwd lng="es"><![CDATA[FOTOCATALISIS]]></kwd>
<kwd lng="es"><![CDATA[M-TiO2]]></kwd>
<kwd lng="es"><![CDATA[TiO2 sulfatado]]></kwd>
</kwd-group>
</article-meta>
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