<?xml version="1.0" encoding="ISO-8859-1"?><article xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance">
<front>
<journal-meta>
<journal-id>0122-5383</journal-id>
<journal-title><![CDATA[CT&F - Ciencia, Tecnología y Futuro]]></journal-title>
<abbrev-journal-title><![CDATA[C.T.F Cienc. Tecnol. Futuro]]></abbrev-journal-title>
<issn>0122-5383</issn>
<publisher>
<publisher-name><![CDATA[Instituto Colombiano del Petróleo (ICP) - ECOPETROL S.A.]]></publisher-name>
</publisher>
</journal-meta>
<article-meta>
<article-id>S0122-53832018000100085</article-id>
<article-id pub-id-type="doi">10.29047/01225383.95</article-id>
<title-group>
<article-title xml:lang="en"><![CDATA[New boron-nitrogen containing modified multifunctional alkylphenolate additives to motor oils]]></article-title>
<article-title xml:lang="es"><![CDATA[Nuevos aditivos multifuncionales para aceite de motor basados en alquilofenato modificados que contienen boro y nitrógeno]]></article-title>
</title-group>
<contrib-group>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Afayat-Khalil]]></surname>
<given-names><![CDATA[Mammadova,]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Vagif-Mecid]]></surname>
<given-names><![CDATA[Farzaliyev,]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
<contrib contrib-type="author">
<name>
<surname><![CDATA[Ali-Kazim]]></surname>
<given-names><![CDATA[Kazimzadeh,]]></given-names>
</name>
<xref ref-type="aff" rid="Aff"/>
</contrib>
</contrib-group>
<aff id="Af1">
<institution><![CDATA[,Azerbaijan National Academy of Sciences Institute of Chemistry of Additives ]]></institution>
<addr-line><![CDATA[ ]]></addr-line>
<country>Republic of Azerbaijan</country>
</aff>
<pub-date pub-type="pub">
<day>00</day>
<month>06</month>
<year>2018</year>
</pub-date>
<pub-date pub-type="epub">
<day>00</day>
<month>06</month>
<year>2018</year>
</pub-date>
<volume>8</volume>
<numero>1</numero>
<fpage>85</fpage>
<lpage>91</lpage>
<copyright-statement/>
<copyright-year/>
<self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_arttext&amp;pid=S0122-53832018000100085&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_abstract&amp;pid=S0122-53832018000100085&amp;lng=en&amp;nrm=iso"></self-uri><self-uri xlink:href="http://www.scielo.org.co/scielo.php?script=sci_pdf&amp;pid=S0122-53832018000100085&amp;lng=en&amp;nrm=iso"></self-uri><abstract abstract-type="short" xml:lang="en"><p><![CDATA[ABSTRACT By carrying out condensation reactions for alkylphenols and methylene-bis-alkylphenols with amines, alkanolamines and formaldehyde, working with boric acid and the neutralization of the obtained product with calcium hydroxide, new boron-nitrogen-containing alkylphenolate, additives have been synthesized (AKI-114B, AKI-212B, AKI-115B, AKI-210B, AKI-214B, AKI-219B). The structure of the obtained - boron esters (derivatives of phenolate) has been studied through the use of the IR spectroscopy method. Simultaneously with studying the functional properties of the synthesized additives in motor oil, it has been established that their detergent, water, corrosion, oxidation and wear resistance properties greatly overbalance the same properties of their single nitrogen-containing and industrial analogues. Through thermoanalytic research conducted on OD-102T typed derivatograph, the high stability (through to 360°C) of additives containing boron-nitrogen has been determined. On the basis of new boron, nitrogen-containing modifications AKl-210B and AKI-115B different motor oil compositions such as M-8B, M-10G2 and etc. have been prepared and tested. The creation of high-synergy efficiency upon interaction of synthesized additives with other ones (sulfonates, dithiophosphates) has been observed, particularly in the improvement of tribological properties, and the increase in the oxidation induction period.]]></p></abstract>
<abstract abstract-type="short" xml:lang="es"><p><![CDATA[RESUMEN Nuevos aditivos para aceite de motor basados en alquilofenatos modificados que contienen Boro y Nitrógeno (AKI-114B, AKI-212B, AKI-115B, AKI-210B, AKI-214B, AKI-219B), se sintetizan mediante reacciones de condensación de alquilofenoles y metil-bis, alquilofenoles con aminas, alcanolaminas y formaldehído. Los productos de reacción se neutralizan con Hidróxido de Cálcio. La estructura de los ésteres de Boro (derivados del fenolato) ha sido analizada a través del uso del método de espectroscopía IR. El estudio de las propiedades funcionales de los aditivos sintetizados para el aceite de motor, ha establecido que sus propiedades detergentes de agua, de corrosión, de oxidación y de resistencia al desgaste superan en gran medida en las mismas propiedades a los aditivos que contienen nitrógeno y aditivos industriales análogos. La investigación termo analítica realizada en un derivatógrafo OD-102T permitió determinar que los aditivos conteniendo Boro-Nitrógeno tienen una alta estabilidad (hasta 360°C). Sobre la base de los nuevos aditivos Boro- Nitrógeno se prepararon las modificaciones AKI-210B y AKI-115B y diferentes composiciones de aceite de motor tales como M-8B y M-10G las cuales fueron igualmente evaluadas. Se ha observado la creación de una alta eficiencia y sinergia tras la interacción de aditivos sintetizados con otros (sulfonatos, ditiofosfatos), particularmente en la mejora de las propiedades tribológicas y el aumento en el período de inducción de la oxidación.]]></p></abstract>
<kwd-group>
<kwd lng="en"><![CDATA[Alkylphenolate]]></kwd>
<kwd lng="en"><![CDATA[Amine]]></kwd>
<kwd lng="en"><![CDATA[Alkanolamine]]></kwd>
<kwd lng="en"><![CDATA[Boric Acid]]></kwd>
<kwd lng="en"><![CDATA[Additives]]></kwd>
<kwd lng="en"><![CDATA[Motor oil]]></kwd>
<kwd lng="es"><![CDATA[Alquilofenato]]></kwd>
<kwd lng="es"><![CDATA[Amina]]></kwd>
<kwd lng="es"><![CDATA[Alcanolamina]]></kwd>
<kwd lng="es"><![CDATA[Ácido Bórico]]></kwd>
<kwd lng="es"><![CDATA[Aditivos]]></kwd>
<kwd lng="es"><![CDATA[Aceite de motor]]></kwd>
</kwd-group>
</article-meta>
</front><back>
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